The filler metal is 4145, preheat to 150 degrees F, let the casting cool in 70 degrees F or warmer air when the welding is complete. Make sure the casting is completely free of any grease or oil, use carbide burrs for joint preperation and a clean degreased stainless steel brush for oxide removal. If you don't have a TIG welder, find someone that does, Mig would be tough. Make sure you do a crater fill technique at the ends of your welds, if you don't you will get cracking in th weld.
Regards, Brad
Brent,
Are you saying you think you have A242? Or, your sure you do?
Just asking because I'm not sure. A356 is often used for cylinder heads.
Be careful where you use 4145 or 4043 on your casting. Those fillers have about half the tensile strength of A242. Your looking at about 40 ksi compared to about 24 ksi (I could be off a little).
If your repair is in the valve seat area, I would be concerned with those fillers. I might look into the possibility of using parent metal if that is the case. Some casting alloys are available in rod form. You might call your local welding supply.
The advice about TIG is good advice.