You are going to have to do some investigating.
First, there is not a PWHT code. There is a code (quite a few actually) that has PWHT requirements. For example, ASME sec VIII for pressure vessels has requirements for PWHT. B31.3 for process piping has requirements for PWHT. AWS D1.1 for structural welding has requirements for PWHT. See what I'm getting at? You are dealing with a pressure vessel, that supposedly is built to ASME sec VIII, so this is the code that would govern if PWHT is required. No other code applies - not B31.3, not D1.1, not API 1104, not ASME sec I, II, III, IV, V, etc., not any of them other than the code to which it was built.
By presure boundary, the post above is referring to any componant that is containg pressure, i.e. the shell, the head, the nozzle, the flange, the re-pad, etc.