Just to add wrought iron is passive because of the slag inclusions, similar to say corten steel. The wrought iron will corrode until a layer of slag is reached and then it will remain. Many old gates, door handles and fences throughout europe are wrought iron dating back over 100 years and it still has not rusted away.
I knew a welder who made decorative gates etc and you still can buy "real" wrought iron from a few specialty mills left in the country. I always heard to use austenitic stainless fillers or braze it.
I could be completely off base but I was under the impression that austentic stainless steeks are more capable of handling the silica slag inclusions and are less likely to fom inclusions or porosity themselves. I know tig welders have been known to use 308 or 309 filler on pipes to rid porosity and there was a rather infamous thread about that
http://www.aws.org/cgi-bin/mwf/topic_show.pl?tid=13901;pg=1 I believe this was due to the mechanic of the metallurgy and the ability to hold the inclusions in the grain structure. Anyone care to shed light on how this works?
a quick look at a phase change diagram will show you that at extremely low levels of carbon it will form alpha ferrite off the top of my head. I can't remember much but off the top of my head pure iron (which as far as I know isn't used for anything) is welded readily.