I don't believe the shielding gas or mixture of gases is an essential variable for welder performance qualification. As such, the welder qualified with any gas shielding is qualified for all gases appropriate for the process.
I believe the intent is that if a prequalified WPS or a qualified WPS is used, the shielding gas is an essential variable for the WPS, not performance qualification.
That being said and with over twenty years in the field as a CWI/SCWI, I would not be surprised at anything. The combinations of gases I've seen folks attempt to use with their prequalified WPS would raise the hair on the back of your neck. I have some renewed hope that some of the problems can be mitigated with the inclusions of clause 3.7.4 in the new 2008 edition of AWS D1.1.
Best regards - Al