Aevald, my response was more about running self shielded FCAW over SMAW or vice versa as I took this to be the question. My information comes from the "Fabricators and Erectors guide to Welded Steel Construction" written by Omer Blodgett, Scott Funderburk and others. There is a really good explaination under Intermixing of Weld Deposits.
It explains about aluminum pick up by other processes when run over the self shielded FCAW. It seems that the FCAW process uses aluminum as a de oxidizer, while SMAW typically uses manganese-silicon and the two are not compatable. If you were to google the title in parentheses above Im sure you could find the whole article.
Dave
I'm not Dave, but here's my two cents. The 6010 and 7018 rod , I am told, is the esentially the same steel. The difference is that the 6010 flux allows the steel to cool faster. That makes it harder and more brittle, Whereas the 7018 flux lets the steel cool a little more slowly and makes it softer, allowing it to "give" a little when stressed.
If you put the more brittle metal(6010) over the softer metal,(7018) the difference in the rate of cooling would cause internal stresses of the weld as a whole.
Just my theory.
Jeff