I checked the miliary filler metal specification, MIL-E-21562, and AWS A5.7. MIL-EN67/MIL-ER67 and ERCuNi appear to be very similar with respect to tensile strength.
I'm not sure what you are attempting to do. If you are tryng to obtain approval to use the AWS filler metal, you will have to demonstrate the filler metal/base metal combination works, i.e., qualify the WPS by testing to NAVSEA TP248 and have the necessary material certifications for the electrodes that will be used.
If you are using filler metal from your current stock or that of your supplier, you can do the requisite testing by qualifying the WPS per TP248 and the filler metal in accordance with MIL-E-21562 (MIL-EN67 or MIL-ER67). The catch is all the filler metal used for the qualification and production will have to come from the same heat number.
In any event, it will take considerable time and expense to qualify the WPS and the filler metal.
We could be more helpful if we better understood what you are trying to do.
Best regards - Al