This is on that job I posted pics of. These are 5/8" bolts we tightened using a cresent wrench and a 15/16" box wrench. We were standing there talking and we heard a loud "Ping!!!". We sat there looking at each other saying, "what the f...udge was that?". I started running the wrench around the bolts and low and behold found the first one with the head popped off. After about 15 minutes we heard another "PING!!" and found the second bolt with the crack in the hex head. When I worked for Caterpillar I know a 5/8" bolt torqued to 200 ft/lbs and we would hammer on them with a 1/2" impact all day long and never once did I see one break or have this happen.
I try to buy my bolts from a local supplier that has most all of the product USA made. Sure they cost a little more, but for the stuff we do, do you really want to worry about the extra 25 cents a bolt.
There's a million things that can go wrong with bolts when they're being made. Cheap suppliers don't do all the right steps in manufacturing or quality control.
If you look at the photos of the broken bolts you can see a couple interesting things.
First, I'm color blind, but the surfaces of the breaks look like they have light rust/red discoloration. If this is true, then the bolts cracked a long time before you ever put a wrench to them. High strength fasteners are heat treated to achieve the right strength. If the quench and temper isn't done correctly, the bolts can crack as they cool.
Second, usually bolts fail from cracks starting where the head meets the shank of the bolt, or from cracks starting in the bottom of the threads. These might have started from where the head meets the bolt shank; its tough to tell for certain. Bad forming operations can leave defects, just like undercut on the toe lines of a weld that will cause bolts to fail prematurely.
Third, and really interesting, in the photo you can see some hair-fine lines that radiate from the center of the fracture surface like spokes on a wagon wheel. These lines are often a sign of fatigue. I can't say for sure if these are fatigue failures from the photos posted, but that would be odd to see on a brand new bolt. Any chance these were re-used somehow?
Lastly, the bolts look to be coated. If the coating is an electro-plating or hot dip galvanizing, then the bolts can be damaged if they aren't properly baked immediately after the coating process is done. Hydrogen embrittlement can cause just the kind of cracking and failure you're seeing here.
Other than mis-use, all of these failure modes are signs of poor quality manufacturing. It would take a more detailed examination by a metallurgical lab to say for certain why these failed, but the odds definitely favor failure by bad manufacturing practice.
It's not just bolts these days. I have seen flanges crack, brand new parts that won't thread together, and poor fitup (out of round) all from imported pipe fittings...
Just my $0.02....