Hi,Having searched an spec. for a project, I've come across a document necessitating an Aluminum thermal spray process on stainless steel 316L for offshore applications. Does anyone know what the reason is? Isn't that being stainless sufficient for it? Edit: Or is that supposed to be used as an insulation?
I have not heard of it, but would consider these (2) somewhat conflicting points:
1) Aluminum is less noble than stainless steel, so the aluminum would give some protection against galvanic corosion, and if the stainless is in contact with aluminum parts, the stainless would not form a galvanic cell with those parts as long as the aluminum coating was intact.
2) Stainless steel needs contact with air/oxygen to maintain it's chrome oxide film, which is what protects it from corosion.
Now that makes it just as clear as mud, doesn't it.
Thanks Niekie & Giovanni, I had not considered SSC, altho I am aware of it. I am trying to learn at a faster rate than I forget.
I resemble that remark Dave! Best regards, Allan
Hi Ehsan
Thermally Spayed Aluminium (TSA) is a very common coating off-shore. More so on carbon steels, but can also be used on S/Steel. TSA has a two fold protection method. Firstly it is a barrier (Aluminium forms a very adherent oxide skin that resists marine corrosion well, but the TSA must be "sealed", as the TSA is somewhat porous.) and secondly it acts as cathodic protection, should the coating be damaged.
Why on S/Steel? Keep in mind that at slightly elevated temperatures, in the presence of chlorides, (sea water) austenitic stainless steels will suffer from Stress Corrosion Cracking (SCC) TSA is sometimes called for in the case of S/Steel in marine environments that will see temperatures in excess of about 60°C. Will also help prevent pitting.
Regards
Niekie
Offshore applications mean the presence of salty water, i.e., water with 3 - 4% of sodium chloride in it.
Austenit stainless steels (AISI 316L is one of them) are subject to stress corrosion in the presence of chlorides. Stress corrosion means that the two factors must be present: stress and chlorides.
On the other hand, aluminum is resistant to water and inmune to chlorides. That's the reason of aluminum spraying on 316L pieces.
No matter if the pieces are above sea level. In offshore applications there will always be the presence of a salty environment.
Giovanni S. Crisi
Sao Paulo - Brazil