The NBIC handles rules for existing boilers requiring repair and modification however ASME Boiler and pressure vessel code Section I addresses power boilers. The rules are contained within those codes. One other thing to consider is your individual state. Some states may have requirements that exceed those of ASME Sec I or the NBIC.
In most cases the 1st valve is a joint ASME SEC I/ASME B31.1 . Which would require the contractor performing the work to be an ASME/NBIC "R" stamp holder. The suitability of a specific valve for a boiler is something that should be decided by the designer of the system.
If no 1st valve was supplied with the unit then in my opinion this is a weld that would fall under the requirements of an A/S/R stampholder (depending upon the exactly what you are doing) .
After the 2nd valve on systems with more than one boiler is usually the end of "code stamp" requirements for the contractor. Still ASME rules, but no requirement for stamping.
With all of the above being said. I am a welder. I strongly suggest you look into the requirements as stated in your state or other jurisdictional laws regarding working on boilers. Normally every state has a "Boiler Inspector" Call them.
I guess the whole thing that is disturbing is that you are asking this. I would think someone in your organization would have this figured out.
The question warrants much more than I can explain. I don't expect the QC Manager or the Engineer to be able to reach 4 tubes deep in a superheater and make a repair in a mirror, and they shouldn't expect me to tell them what the tubes should be made of.
You can get your start on understanding some of these complexities by looking at these graphics.
http://cstools.asme.org/csconnect/PDF/R010125.pdf . These may or may not be current.
Have a great day.
Gerald Austin