Back to my initial response as my starting point; either the WPS is prequalified and meets all the conditions of prequalification, including the prequalification of all materials within the joint, or the WPS must be qualified by testing.
Assuming it is recognized that one or more of the components in the welded assembly, i.e., the joint, are not prequalified, qualification by testing is required. For materials not listed I Table 3.1 or 4.9, see Table 4.8, last line, the WPS is only qualified for those materials listed on the PQR. That being the case, one would have to know the pedigree of the materials used, including the material that was used as a spacer (slugging material in your case) to comply with Table 4.8.
Let's not forget that the materials used for slugging are defined as unknown or unauthorized materials. That would exclude them from use when welding the test assembly.
Al