I have to agree with Lawrence on calling Hydrogen Induced Cracking otherwise known as "HIC" or Hydrogen assisted cracking "HAC"
What are some of the most common causes to this problem? It's important to note that the Ionic/atomic hydrogen that is entrapped in Al as a result of the presence of water, and/or hydrocarbons is not the same as dry gaseous Diatomic hydrogen gas originating from a pressurized cylinder... In other words, Ionic/atomic hydrogen is much smaller than normal diatomic/molecular hydrogen mainly in size... The smaller of the two types is the Ionic/atomic gas that is usually segregated from either moisture or some form of hydrocarbon and then diffused into the metal... When ionic hydrogen is produced such as during arc welding, or welding in a wet environment, it may indeed cause embrittlement of both ferous and non-ferrous metals... Certified welders prevent this with proper techniques such as cleaning, preheating and keeping their work pieces dry during welding... A properly constructed steel pipeline that currently caries natural gas can also transport hydrogen without a problem...
Here's a short list of possibilities:
1.) Humid environments and condensation or puddling of water on the surfaces over a period of time of the base metal to be joined and the same goes for the treatment of the filler metal and it's exposure to a humid environment, or becoming wet on the surface also...
2.) Shielding gas dew points is too high usually from excessive moisture mixed with the shielding gas resulting in atomic hydrogen diffusion into various metals...
3.) hydrogen from any type of hydrocarbon such as: grease, oils, water based cutting fluid used in machining some cleaners that don't really degrease the metal, and instead introduces a very thin layer of hydrocarbons on the surface... I would like to discuss this further but, I need to hit the bunk because I need to be ready by 6AM to go for dialysis treatment so I need to stop here...
Below are 3 websites and a book recommendation that get down to the nitty-gritty of some modelling methods used in prevention as well as studying the mechanisms which result in HIC or HAC.
http://www.slideshare.net/tkgn/hydrogen-damage?related=1http://www.vsgc.odu.edu/src/Conf2010/Grad%20Papers/Francis%20-%20Paper.pdfhttp://arxiv.org/pdf/cond-mat/0503483v1.pdf"Welding Metallurgy and Weldability" by John Lippold and, The Welding of Aluminum and Its Alloys by Gene Mathers:
http://www.amazon.com/s/ref=nb_sb_ss_i_2_18?url=search-alias%3Dstripbooks&field-keywords=welding+metallurgy+and+weldability&sprefix=Welding+Metallurgy%2Cstripbooks%2C250 Lippold
http://www.barnesandnoble.com/s/welding+metallurgy+and+weldability?_requestid=255972 Lippold
http://www.amazon.com/Gene-Mathers/e/B001KIKB0A <------- Mathers
/
http://www.barnesandnoble.com/w/welding-of-aluminium-and-its-alloys-gene-mathers/1101586491?ean=9780849315510Respectfully,
Henry