Tim,
If welding a stainless flange to the stainless pipe is out of the question and then bolting the two together, then I would suggest the following.
1. For direction, you might consider AWS D11.2-89, "Guide for Welding Iron Castings".
2. Special Metals Welding Products (formally Inco Alloys) provides a wealth of technical assistance for this type of joint and others..
3. Consider Nirod 44 or Nirod 55 for the joining of cast irons to themselves and wrought carbon steels and austenitic stainless steel.
4. You might consider performing a spark test, (crude I know), to determine carbon content of casting, or scrapings for metallurgical analysis.
5. Pre- heat, anyone's guess to the time at temp, etc, etc.
John Folk