Hello Pete,
Let me see how well I recall the details...
Anodizing involves the formation of of an aluminum oxide matrix on the surface of the aluminum, which matrix is naturally pourous. These pores are optionally dyed with a decorative color if desired, then sealed, which protects the substrate with a thin film of what is technically a ceramic. I believe the soda bath acts on the substrate, a detail upon which I would welcome correction. In any event, the anodized surface, I recall, is an excellent base for paint- although I am not recalling with total clarity. There are pretreatments and additives available for certain organic coatings (paint) to improve adhesion for use on aluminum, according to the coating system selected... You should be able to achieve excellent results with any variety of pigmented colors, and I suspect results would be quite acceptable if you were to strip the entire anodize film, polish and clearcoat with an appropriate coating formula. Such finishes are providing outstanding finishes and durability on brass door hardware exposed to direct sunlight and weather, as well as plumbing fittings.
Technical information on professional coatings is usually quite easily obtained from the manufacturers (eg: DuPont) but surprisingly you can learn all you need to know with the help of a local Sherwyn-Williams representative. You want a "professional coatings catalog", and not all of the coatings are available for sale in all states or to the general public. My guess is you will be selecting some kind of polyurethane based coating.
I thought that follow-up was a nice thought for all of us, and perhaps the information I have given will provide some food for conversation with your chemist friend and perhaps lead to the color solution you wanted.
It's inappropriate to apply a cold galvanizing, zinc-rich paint to the surface of aluminum. Zinc works on the surface of steel to inhibit corrosion by combining with the oxygen before the iron in the steel. It corrodes- thats what oxidation is, after all- sacrificing itself to preserve the substrate.. indeed it's classified as a sacrificial coating (as is cadmium). Aluminum on the other hand combines very readily with oxygen to form an oxide layer which, conveniently for mankind, serves as a barrier to prevent oxygen from coming in contact with the "pure" (or at least unoxidized) aluminum below. The rapid formation of this handy oxide is one of the phenomenon which makes aluminum difficult to weld.
Sorry I didnt spot this post earlier, but I hope I helped you find a more attractive coating to protect your work.
Unfortunately Ive been distracted. I had some bad news at home and the kids were quite disrought. While working on a piano restoration project our pet canary escaped, flew into a closed windowpane and fell, unconcious, into an open can of paint. Although it was a tragic loss and we'll miss him terribly, at least he had a fine finish.
Regards
d