Hi Andy,
There was more discussion in the past about stellite to stainless, I don't remember if duplex was mentioned though. GRoberts, Brande, jon200013, Giovanni Crisi, and others have posted regarding stellite overlays and I think there was mention of buttering with inconel.
Try searching again for "stellite" and change the days to "999" and limit posts to "100", and that should find those past discussions. Sorry, but I don't have any experience with those materials to share, only what I've read in the forum.
Hope this helps,
John Wright