I would contact Praxair for info on UV levels. They have a lot of good literature. I'm sure a web search will find other sources too.
If I had to guess, I would say the 95% Argon mixture would produce a higher level of UV simply because it has been researched and found that an arc in argon produces a higher level than with a CO2 atmosphere.
I have to say that all this sounds like trying to figure out which is worse, burning your hand on 500 deg steel or on 550 degree steel?
Chet Guilford