There is exothermic welding and brazing that use essentially the same process. The exothermic process uses a chemical reaction to produce/generate the heat required to heat the joint up to temperature. I do not know if the compound used to produce the chemical reaction is always the same for welding and brazing. Most likely the compound varies depending on the temperature that is needed to be reached. You may want to contact companies like Cadweld, Thermoweld, and Techweld, they may be able to provide you with more specifics about the compounds.
-Creed Darling