Hotpass,
Have to agree with Hogan, on this one. The D1.1 does have pre-qualified groupings for the steel(s) to be used. If the material is not specifically metioned in one of the groups, then I would consider it to be unlisted.
Not too certain but, S355K2+N might be under the EN 10025 standard for European Structural Steel.
The unlisted material limits you to that specific material used in the PQR. It is stated in one of the tables in Section 4, sorry Clause 4. Table 4.9 or some where around there.
Hope that helps.
Without more information (a typical copy of a Material Test Report) the only thing I found out is its a 50ksi typical yield, (345 to 355 MP depending on thickness) and + being bendable quality and is listed as very weldable.
Can you post a typical MTR copy?