By 803056
Date 05-25-2012 21:14
Edited 05-26-2012 03:34
The copper flash is volatized by the heat of the welding arc. OSHA raised the flag back in the later part of the 70's / early 80's and made the manufacturers eliminate the copper flash because the copper was considered a heavy metal. The filler metal would rust so quickly it became clear that the steel wire needed some form of protective coating and OSHA caved.
Copper melts at about 1981 degrees F while steel metals at higher temperatures (2500 - 2800) depending on the carbon content. No carbon/low carbon steel melts at temperatures around 2800 and as the carbon is increased, it melting at temperatures closer to 2500 degrees F. Copper, being a low melting constituent stays liquid in the molten weld pool until the temperature drops below 1981 degrees. It has very low solubility, thus only a small fraction goes into solution with the iron. The copper usually solidifies along the grain boundaries and usually toward the centerline of the weld bead since that is the last region to solidify. That isn't to say it will not segregate toward any grain boundary when the solidification is rapid as is the case with stringer beads.
I use copper to induce cracks for test samples used for NDT training. A very small whisker of copper wire from a welding lead is one of the easiest ways to cause a weld in steel to crack.
As for an inclusion, I don't know. As noted, the copper usually is found along the grain boundaries rather than in a "clump" as is the case of tungsten which has a melting point well above that of steel, i.e., 6100 degrees for tungsten versus 2500 to 2800 for steel. Tungsten usually appears as a rounded indication that appears to be very white compared to the surrounding area.
As for the radiographer calling a less dense indication a copper inclusion, I don't know. I've had that happen when there was spatter on the face of the weld and I've read RT reader sheets reporting slag inclusions when the weld was made with GTAW. Go figure!
Best regards - Al