Then I'll call you - Kara,
many thanks, and thanks also to "welderbrent".
Definitely I intend to finish, what I was starting here.
Hopefully I'll not be going to disappoint you and "welderbrent" too much when coming to my summary in very due time.
I'm thinking about whether I must ask you to accept my apologies again, for the "
hard times" you have. But I decided not to apologise, because I mean it's good, learning it "this" way. That makes the brain cells valuably working for forming new synapses and; everything too quickly understood, does not last that long in mind, at least that is the case with me.
And finally, it makes me glad to see you saying: "…
but I think I'm starting to understand."
I can also see, you're asking questions. That is good. That is very good.
You ask: "
What is fluorine? From what you're saying it’s part of the flux, right?"
I reply: Fluorine is one of a high number of elements, structured in the periodic table of the elements. Please ask Lawrence and I'm sure he will be happy to explain this in greater detail to you. Please use also this link:
http://www.webelements.com/fluorine/atoms.html, for deeper explanation of 'Fluorine'. Briefly, Fluorine is the chemically most
reactive of all existing elements. That means, it is heavily aiming at producing compounds with other elements, e.g. Calcium. The new "substance" created from this is even
calcium-fluoride (denoted CaF2). It is used in basic electrode coatings because it's helpful in lowering the viscosity of the slag formed upon your weld bead, originally arising from your electrode coating.
You ask: "
You are comparing dc negative and dc positve with the smaw process, and your saying dc negative have more negatively charged particles, right?"
I reply: I have just even begun to deal with some very details of the SAMW process as when it comes to what's going on at both electrical terminals; i.e. your stick electrode and your workpiece/weld pool.
You ask: "
And since negative charged particles, the electrons I mean, are what carry the current that's why the one polarity has more penetration?"
I reply: Yes! You have understood.
You may probably ask. Is all this really needed just to answer such simple questions? And I honestly consider all this (and actually even much, much more) necessary due to having in mind Lawrence' statement, saying: "
With the 6013 EP is definitely better for penetration."
Hence, if we would not treat an electrode type different to E6013, how should we try to estimate the reasons and causes then for some particular amount of "penetration"? I thus stick to dealing with the AWS 5.1 E7018, simply because to me it's the most adequate piece of filler metal to describe what is going on in a close distance to the electrode tip.
Resume, thus.
So, last we heard that a higher arc voltage is measurable using basic covered electrodes at straight polarity. This leads to some "sharp" acting arc, perturbed weld behaviour and unstable droplet detachment, joined by an increase in spatter.
However, how about
SMAW-EP using AWS 5.1 E7018?
Choosing this polarity now the workpiece emits electrons moving toward and hitting the anode (electrode). This, highly heated up thereby, again produces Fluorine ions by dissociation of CaF2 (recall the electrode coating). The Ca+ ions are attracted by the cathode (workpiece) this is agreed, but how about the Fluorine ions? Well, these are attracted by the electrode itself of course, due to being positively charged. They are found almost instantaneously absorbed again as they're no further required to cross the whole arc gap (plasma column) to reach the opposite positive. That causes both an increase in arc stability (uniform arc attachment, termed
anode spot, at the molten droplet) and an additional heating effect at the droplet surface. This additional heat is transferred to the workpiece/weld pool again by the molten droplet, whose heat content may be suggested higher vs. DC-EN. Finally, however, (E7018) SMAW-EP is running visually more stable vs. SMAW-EN.
Strange! Haven't we heard actually that – in non-consumable electrode GTAW – the cathode emits electrons and the anode may be supposed "hotter" thus, due to being permanently hit by these electrons?
Shouldn't we further consider these laws of physics to govern also our E7018 DC-EN application?
What about our penetration depth, then? Shouldn't it be "greater" thus using EN7018 at electrode negative?
We actually should be able already to deduce the answer from what's been discussed as yet. But wait. We need to consider one important detail. In a basic electrode arc the electron density (the number of electrons across the whole arc plasma volume) is reduced. Why this? Simply speaking, this is also due to the accumulation of negative charge carriers in front of the molten electrode tip, even where dissociation of CaF2 into Ca+ and 2 F- occurs.
For a better understanding, one further detail becomes important, thus it needs appropriate mention.
The area that accumulates the negative charge carriers (negative Fluorine ions and electrons) is joined by one interesting phenomenon, quite having the power to "shift" all those boundary conditions in charge of a smooth electron emission towards the anode. It is termed '
space charge'. Unnecessarily complicating the whole subject I'll pass up treating this here further. However, this space charge, a result from the surplus of negative charge carriers in front of the molten electrode, significantly impedes electron transition to the arc column allowing them thereby to be transmitted to the anode.
It importantly changes also the height of the anode's
attractive force, regularly acting upon each single negative charge carrier to finally "capture" it. Hence, the amount of electron condensation at the workpiece is reduced due to the:
- decreased number of electrons in the arc column, caused by
- changed conditions in front of the electrode, which causes a
- change in the space charge conditions, that
- impedes the electron emission to the plasma column.
Here we come full circle.
Because due to the reduced electron condensation at the anode, often treated as a representative for "heat" transfer to the anode, we may suggest the cathode (electrode) to be "hotter", and thus assumingly weld fusion depth may be found decreased at the workpiece applying direct current electrode negative.
I did never investigate this by myself as yet, but, actually, and according to what I was allowed to learn (a number of years ago
much greater than your own age, Kara) that should prove, at least to me, a somewhat logical consequence from all of this. By the way, this is what makes this thread so interesting, because the questions are so fascinatingly interesting.
Thus, I suppose if not even a "deeper", but at least a significantly changed penetration profile to occur – always presuming "regular" (whatever this is) boundary conditions given – with
DC-EP.
However and by all means, I’ll be back soon, for what it’s worth. Because slowly, I suppose, we have to draw some conclusions, don't we?