Hi,
This link will take you to a site with electrode selection. If you click on a particular reference, it takes you to a page with a description, application, weld metal chemical analysis, as welded mechanical properties, current, sizes, and amperage.
http://www.mwa-international.com/products.asp?ID=6
I don't know if this is related to your problem, but copper-nickel alloys are susceptible to lead or sulfur embrittlement. For welding, the phosphorus and sulfur levels in these alloys are normally held to a maximum of 0.02 percent. Another thing worth mentioning is that contamination from sulfur bearing marking crayons or cutting lubricants will cause cracking during welding. Also, if the material is above 3mm thick, you may want to use a v groove, with an included angle of 70 degrees or above, because the molten weld metal is not as fluid as with carbon steels and needs manipulation of the electrode to ensure fusion of the side walls. Also, welding with covered electrodes should be done in the flat position, although small sizes can be used in all positions. As John said, a little more information is needed. I'm just throwing out a few things for consideration.