Hey, two things to keep in mind, sil fos, or RBCuP doesn't require a flux on copper to copper so if your trying to go copper to brass then yes, the flux will assist with that effort. Problem with using either RBCuP or Silver brazing RBAg alloys is melting and flow temps. More heat into the brass is required and the silver brazing alloy depending on joint design, probably not a good fit due to range of flow between solid and liquid.
Clean the surface well, flux even better, protect what you can from the heat, and focus it more to the brass. Slow and steady rise of heat. Once the flux starts to do it's thing, your off to the races.
Between you and me, it should work. But good luck with that effort.