The welder cannot apply the 'As Detailed' tolerance, only the drafter/detailer can use that tolerance.
Welder can only apply the 'As Fit up" tolerance.
That is the purpose of the differential between As Detailed and As Fit up.
For the purpose of the D1.5 qualification, you are the detailer (as the one 'designing' the WPS). You detail it as 30° angle with a 3/8" root opening, the welder than fits it up and uses the tolerance to achieve a 25° angle with a 5/8" root opening. The fit-up test then meets the requirements of the NYSDOT test.
You can detail your NYSDOT qualification as 20° angle with a 5/8" root opening, the welder fits it up with a 25° angle and a 5/8" root opening.
As for position tolerance, that is something of a dispute among most CWIs. Proceed at your own risk in utilizing any, as some say there is no tolerance for positions on tests, others say otherwise. Your NYSDOT inspector/witness will tell you what they will allow.