Ken,
What material are you brazing? 6061? 6063? something different.
For 6XXX, we find 1100 wire works best.
YOu can also use a few different designs for putting the peices together. If you have a stable tab and slot configuration that can be used for self fixturing, you can use a prick punch or staking to hold the parts together witht eh proper gap and then just weight the parts down with a light fixture to keep it from possibly floating in the flux.
Otherwise, fixturing will depend on the size, complexity and shape. It can be as simply as using perferated stainless steel with a light spring on the outside edges. Complex stuctures can use dozens of plates, springs and other fixturing techniques.
In short, there is too little info on what you are trying to acheive.
Sean